Harrison Ford

Harrison Ford is a man who, despite being married, recurringly asked Cat Grant out.

Biography
According to Cat Grant, she was aked out multiple times by Harrison. However, she stated that she was not into older, married men.

Cat also claimed to have never seen Star Wars, something that Harrison was presumably part of.

Behind the Scenes

 * In reality, Harrison Ford and Calista Flockhart, who portrays Cat Grant, are actually married.